THE
GRASS TURNS GREENER
Bio-mass has emerged as a promising environment
friendly source of energy. The term bio-mass means
anything that is of biological or botanical origin.
It is material from living, or organisms which
have been living till recently, like wood, waste,
gas, and alcohol. Usually biomass refers to vegetation
grown to generate energy. In this sense, living
plants can also be included, as they can generate
electricity.
Before
the industrial revolution bio-fuels used to be
the principal source of energy all over the world,
and even today on an average it supplies around
five percent of the energy consumed worldwide,
with most of it accounted for by the Third World
household sector. In the US, bio-fuels account
for three percent of the energy consumed.
Biomass
energy is derived from five sources. They are
garbage, wood, waste, landfill gases and alcohol.
In the case of wood, energy is derived from directly
harvested wood as well as wood waste. The largest
source of energy from wood is pulping liquor or
“black liquor,” a waste product from
the manufacturing processes of the pulp, paper
and paperboard industry.
Waste
is the second largest source of biomass energy.
The main sources of waste energy are municipal
solid waste (MSW), manufacturing waste, and landfill
gas. Biomass alcohol or ethanol is produced mainly
from sugarcane and corn. It can be used directly
as a fuel or as an additive to gasoline.
Plants
like miscanthus, switchgrass, hemp, corn, poplar,
willow, sorghum, sugarcane and many kinds of trees,
ranging from eucalyptus to oil palms are the principal
sources of commercial bio-fuel mass. The plant
used has no effect on the end products, but the
processing of the raw material changes with the
type of bio-mass used like crop or livestock waste
Crop
and livestock waste can be used as biomass. Process
residues, dung and bagasse (sugarcane waste) can
be used for producing bio-energy. Methane is commonly
produced bio-energy source and it is considered
a very efficient fuel.
Another
source of bio-energy is fast-growing trees and
grasses. Many biological material like stalks,
straws, treetops, branches, perennial crops and
forest waste can be used as biomass. Using this,
it is possible to manufacture fuels like ethanol,
hydrogen and methane.
In
fact, bio-fuels can be made from many kinds of
materials. For example, byproducts from the manufacture
of fibers can be used as bio-fuel. The manufacture
of pulp, paper, lumber, plywood and cotton yields
residues like black liquor, sawdust and bark which
can also be used as biomass.
The
wood waste generated by the construction industry,
yard trimmings and non-recyclable organic material
can also be used to produce energy. In fact, it
is possible to manufacture your own alcohol, methane
or bio-diesel from many waste products.
Biomass
includes plant or animal matter used for the production
of fibers and chemicals and biodegradable wastes
that can be burnt as fuel.
However,
bio-fuels does not include fossil fuels, although
they are organic material transformed by geological
processes into coal or petroleum. Although fossil
fuels have their origin in ancient biomass, they
are not considered biomass as their carbon has
been "out" of the carbon cycle for a
very long time. In fact their combustion disturbs
the carbon dioxide levels in the atmosphere.
Bio-energy
producers use bio-mass to produce electricity,
gas, liquids, chemicals and other materials which
can be converted into energy.
Bio-energy
ranks second to hydropower in renewable energy
sources and in many advanced countries it provides
almost five percent of the total energy mix.
Chemical
composition:
Biomass
is essentially made up of carbon, hydrogen and
oxygen. It also contains some nitrogen and small
quantities of alkalis, alkaline earth and heavy
metals. Metals are often found in molecules like
Porphyrins which include chlorophyll. Incidentally
chlorophyll contains magnesium.
Plants
combine water and carbon dioxide to make sugar
building blocks. The energy required for this
is produced from sunlight via photosynthesis using
chlorophyll. On an average, between 0.1 and one
percent of the sunlight is stored as chemical
energy in plants. The sugar building blocks are
the basic constituents of the major fractions
found in all terrestrial plants, that is lignin,
hemicellulose and cellulose.
The
most common way in which biomass is used is still
direct incineration. Forest residues (dead trees,
branches and tree stumps), yard clippings, wood
chips and garbage are often directly burnt.
Biomass
can be converted to methane or fuels like ethanol
and biodiesel. Rotting garbage, agricultural and
human waste release methane, the so called "landfill
gas" or "biogas." Crops like corn
and sugarcane can be fermented to produce ethanol.
Biodiesel is produced from left-over food products
like vegetable oils and animal fats. The production
of liquid fuels from biomass (BTLs) and cellulosic
ethanol is still under research.
There
are many technological means available to use
the wide variety of biomass available. Conversion
technologies can release the energy directly,
in the form of heat or electricity, or may convert
it to another form, like liquid bio-fuel or combustible
biogas. While some types of biomass offer many
usage options, for some we have to use appropriate
technology.
These
are processes in which heat is the dominant mechanism
to convert the biomass into another chemical form.
The basic alternatives of combustion, torrefaction,
pyrolysis, and gasification are separated principally
by the extent to which the chemical reactions
involved are allowed to proceed (mainly controlled
by the availability of oxygen and conversion temperature).
There
are other less common, experimental thermal processes
that may offer benefits such as hydrothermal upgrading
(HTU) and hydro processing. Some have been developed
for use on high moisture content biomass, including
aqueous slurries, and allow them to be converted
into more convenient forms. Some of the applications
of thermal conversion are combined heat and power
(CHP) and co-firing. The efficiency of a biomass
power plant can range from 20 to 27 percent.
There
are many chemical processes available to convert
biomass into other forms, so as to produce a fuel
that can be conveniently used, transported or
stored, or to exploit some property of the process
itself.
Biomass
can also be converted directly into liquid fuels.
The two most common liquid bio fuels are ethanol
and biodiesel. Ethanol, an alcohol, is made by
fermenting any biomass rich in carbohydrates.
Although 100 percent alcohol is combustible and
can be used as a fuel generally it is used as
an additive to cut down a vehicle's carbon monoxide
and other harmful emissions.
Biodiesel,
an ester, is made from vegetable oils, animal
fats, algae or even recycled cooking oils. It
can also be used as a diesel additive to reduce
vehicle pollution.
A
microbial electrolysis cell can be used to directly
make hydrogen gas from plant matter.
As
biomass is a natural material, many highly efficient
biochemical processes exist in nature to break
down its molecules, and many of these biochemical
conversion processes can be harnessed industrially.
Biochemical
conversion processes use the enzymes produced
by bacteria and other micro-organisms to break
down biomass. In most cases micro-organisms are
used to carry out conversion processes like anaerobic
digestion, fermentation and composting.
Another
chemical process used to convert straight and
waste vegetable oils into biodiesel is transesterification.
Biomass is also broken down into carbohydrates
and simple sugars to make alcohol. However, this
process has not been perfected yet.
Heat
can be used to chemically convert biomass into
fuel oil, which can be burnt to generate electricity.
Biomass can also be burnt directly to produce
steam for electricity generation.
Environmental
impact:
Burning
biomass produces carbon monoxide, NOx (nitrogen
oxides), VOCs
(volatile
organic compounds), particulates and other pollutants,
in some cases at levels above those from fuels
coal and natural gas. Black carbon - a pollutant
created by the incomplete combustion of fossil
fuels, bio-fuels and biomass, is the second largest
contributor to global warming.
In
2009, a Swedish study of the giant brown haze
that periodically covers large areas in South
Asia concluded that it was mainly produced by
the burning of biomass, and fossil fuels. Researchers
found a significant concentration of 14C in the
haze, which is associated with recent plant life
rather than fossil fuels.
When
bio-mass is burnt, the carbon in it is released
into the atmosphere as carbon dioxide (CO2). The
amount of carbon stored in dry wood is approximately
50 percent of weight. If the biomass is from quick
growing agricultural sources, it can be replaced
by planting anew. But if it from forests, recapturing
the carbon will take a long time.
The
size of a bio-mass power plant is often determined
by the availability of biomass as transport costs
play a key role. However, rail and inland shipping
can cut transport costs significantly.
Biomass
crops can sequester carbon even after harvesting.
For example soil organic carbon is greater in
switchgrass stands than in cultivated cropland
soil, especially at depths below 12 inches. The
grass sequesters the carbon in its root mass.
Perennial crops sequester much more carbon than
annual crops due to their much greater non-harvested
living biomass, both living and dead, built up
over years, and lesser soil disruption.
The
biomass-is-carbon-neutral theory which was floated
in the early 1990s has now been replaced by recent
discoveries that mature forests sequester carbon
more effectively than cut-over areas. When a tree’s
carbon is released into the atmosphere in a single
pulse, it contributes to climate change much more
than woodland timber rotting slowly over decades.
Advantages:
With
the prices of fossil fuels rising bio-fuels are
once again becoming popular, and one of its great
plus points is that it is possible to grow fuel
in our backyards and thus reduce dependence on
foreign sources.
Another
great plus point of bio-energy is that it helps
to control carbon dioxide emissions (plants absorb
CO2 and this offsets emissions). The use of biomass
to generate energy opens a new source of income
to farmers.
Bio-mass
has some negative points too. The burning of biomass
produces greenhouse emissions. The biggest drawback
of biomass is that it produces carbon dioxide
and other greenhouse gases. It takes more energy
to plant, cultivate and harvest the crops than
the energy they yield. It also uses up more water
and fossil fuels to make the fertilizers and the
fuels for planting and harvesting.
Biomass
collection is difficult and they are not available
throughout the year. Corn, wheat, barley etc used
to produce ethanol are seasonal. Trees are slow
growing even though they are renewable.
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